Utilisation of Accelerator-Based Real-time Methods in the Investigation of Materials with High Technological Importance

Closed for proposals

Project Type

Coordinated Research Project

Project Code

F12024

CRP

1748

Approved Date

18 November 2011

Status

Closed

Start Date

28 March 2012

Expected End Date

28 March 2016

Completed Date

1 July 2016

Description

Accelerators have played an important role in the development and application of nuclear science and technology for more than 60 years. Over the decades, the many different types of radiation produced by accelerators have been harnessed, developed and optimized to support the research and development needs of industry and academia.  Accelerator-based methods can be subdivided into three main areas on the basis of what type of particle beams are used to probe the sample (energy related material) under study: ion/electron, X-ray or neutrons. Synchrotron radiation in particular has many unique properties which make it an indispensable tool in the investigation of matter in modern science, e.g. the continuous emission spectrum of emission, spatial coherence, temporal structure, high brightness, changeable polarization, etc. Complementary to synchrotron radiation are accelerator-based high-intensity neutron beams from spallation neutron sources, and heavy ion and electron beam accelerators, all of which are increasingly being utilized for real-time studies in a wide and diverse range of applications, including sustainable energy systems, protection of the environment or biology. The experimental techniques that use radiation as probe can be classified in three broad categories: spectroscopy, scattering and diffraction, and imaging, all of which can be effectively used for time resolved experiments which can bring new and important information about a variety of physical and chemical processes.  The objective of this new Coordinated Research Project is to stimulate research and development as well as practical applications of accelerator-based real-time and in-situ techniques, specifically in energy related scientific topics, and to grow further interdisciplinary and international collaborations. Real-time material characterization using synchrotron radiation, neutron, ion and electron beams is recognized as a valuable tool to address research and technological questions concerning materials for energy-related applications. This can be addressed through a better understanding of the processes that degrade a material’s performance with use or by ageing. Such materials are essential for the development and successful deployment of next-generation energy sources that are crucial for the successful implementation of a CO2-reduced energy economy.

Objectives

Application of accelerator based real-time and in-situ methods in the investigation of materials that are crucial for future nuclear energy technologies. This responds to recent demand among many Member States regarding cutting-edge research related to energy, applied physics and materials science. The project will help to build-up a knowledge base and lead to the  harmonisation of testing methodologies. The objective of the project 1.4.3.1 (NAPC) under which the CRP is being proposed is: To increase the capacity of Member States to utilize frontline accelerator based methods in order to support their research and development needs to stimulate exchange of information and best practice and to contribute to international consensus in the R&D efforts related to the energy storage and conversion.

Specific objectives

Contribution to the solution of pending research and/or technological issues through the effective application of real-time and/or in-situ accelerator based methods

Development of a knowledge base with recommendations for the specific real-time and in-situ characterization of materials (including methodology and test matrix)

Enhancement of international collaboration and capacity building in the application of real-time and in-situ nuclear techniques, specifically for the investigation and characterisation of materials.

Harmonisation of methodology for the benchmarking of the achieved experimental results in the area of materials for energy applications (solar cells, energy storage and radiation resistant materials for application in the nuclear industry).

Identification and selection of specific research issues related to energy storage and conversion in order to promote accelerator based techniques and their added value

Contribution to the solution of pending research and/or technological issues through the effective application of real-time and/or in-situ accelerator based methods

Development of a knowledge base with recommendations for the specific real-time and in-situ characterization of materials (including methodology and test matrix)

Enhancement of international collaboration and capacity building in the application of real-time and in-situ nuclear techniques, specifically for the investigation and characterisation of materials.

Harmonisation of methodology for the benchmarking of the achieved experimental results in the area of materials for energy applications (solar cells, energy storage and radiation resistant materials for application in the nuclear industry).

Identification and selection of specific research issues related to energy storage and conversion in order to promote accelerator based techniques and their added value

Impact

This CRP collaboration had a significant impact on the below aspects:

• Research output-The results achieved during this CRP cover a broad range of fabrication and characterization of materials related to energy, such as the radiation hardness of Zr- and Ni-based alloys and multi-layered ceramic coatings, the study of lifetime and efficiency of polymer-based novel materials for solid oxide fuel cells, examination of anti-reflection coatings for increase the efficiency of Si-based solar cells, study of the key performance indicators in TiO2 photocatalytic material, characterization of Pb-Bi alloy for liquid metal cooling of fast neutron reactors.
• Capability and capacity enhancement-Several participants to the CRP (CMAM, NECSA, IAP-NASU, JINR and NOAR-ESRF) used this opportunity to enhance their capabilities and expand on their capacity to investigate energy-related materials. This increased capability and capacity will be accessed by the wider scientific community through the open access process (e.g Elettra, ANSTO, NOAR-ESRF, JINR).
• Educational aspects – CRP participation provided the ability to involve student (Masters and PhD) and young ‘early career’ scientists. Funding for attending conferences, workshops, as well as performing analysis at other participant’s laboratory facilities was partially provided through this CRP.
• Greater collaboration - CRP involvement provided opportunity to expand/establish new international networks from which collaborations (both within and outside of this CRP) have been formed.
• Increased knowledge –A number of participants cited that involvement in this CRP provided them specifically with new knowledge on available accelerator-based complimentary techniques they were previously unaware of.

Relevance

The work implemented within this CRP and results achieved are fully relevant to the IAEA programme as:

1) Utilization and further development of nuclear techniques (using ions, x-rays, neutrons and electrons) both for irradiation and analysis;
2) Improved understanding of material modification and radiation damage;
3) Investigation of energy related materials for energy production and energy storage;
4) Networking and knowledge transfer.

CRP Publications

Type

scientific paper

Year

2014

Description

V.A. Skuratov, J. O’Connell, N.S. Kirilkin, J. Neethling. On the threshold of damage formation in aluminum oxide via electronic excitations. Nucl. Instr. Meth. B 326 (2014) 223–227.

Country/Organization

Russia

Type

PhD thesis

Year

2013

Description

Hatala T.: The use of synchrotron radiation in the study of nanocrystalline alloys, Slovak University of Technology in Bratislava, June 2013, Bratislava, Slovakia (supervisor M. Miglierini)

Country/Organization

Slovakia

Type

scientific paper

Year

2014

Description

Vladimir Martis, Andrew M. Beale, Dirk Detollenaere, Dipanjan Banerjee, Martine Moroni, Fabrice Gosselin and Wim Bras. A high pressure and controlled flow gas system for catalysis research J. Synch. Rad. 21(2),(2014), 462 – 463.

Country/Organization

Netherlands

Type

scientific paper

Year

2013

Description

Vladimir Martis, Richard Oldman, Ross Anderson, Martin Fowles, Tim Hyde, Richard Smith, Sergey Nikitenko, Wim Bras and Gopinathan Sankar. Structure and speciation of chromium ions in chromium doped Fe2O3 catalysts Phys. Chem. Chem. Phys., 2013, 15, 168-175

Country/Organization

Netherlands

Type

scientific paper

Year

2014

Description

Miglierini M. and Pavúk M.: Mössbauer and MFM investigations of surface magnetism in NANOPERM nanocrystalline alloys, Acta Phys. Pol. A 126 (2014) 124-125

Country/Organization

Slovakia

Type

PhD thesis

Year

2013

Description

A.Kramchenkov. High resolution elastic scattering spectrometry of ion beam, 2013, PhD thesis, Sumy, Ukraine (in Ukrainian)

Country/Organization

Ukrain

Type

Master thesis

Year

2014

Description

N.Iriyama, Bragg-edge analysis of nickel-base alloy processed by grain boundary control using pulsed neutron transmission spectroscopy, 2014. Master thesis, Hokkaido University, Japan

Country/Organization

Japan

Type

scientific paper

Year

2014

Description

R. K. Bommali, M. H. Modi, S. Zhou, S. Ghosh and P. Srivastava, “Study of Growth Kinetics and Depth Resolved Composition of a-SiNx:H Thin Films by Resonant Soft X-Ray Reflectivity at the Si L2,3-Edge”, Applied Surface Science. 305 (2014)173.

Country/Organization

India

Type

scientific paper

Year

2014

Description

J. Perrière, C. Hebert, N. Jedrecy, W. Seiler, O. Zanellato, X. Portier, R. Pérez-Casero, E.Millon, M. Nistor, J. Appl. Phys. 116 (2014) 123502.

Country/Organization

Spain

Type

scientific paper

Year

2013

Description

M. Obradovic, D. Pjevic, D. Peruško, A. Grce, M. Milosavljevic, K.P. Homewood, Z. Siketic, “Effects of helium ion irradiation on bubble formation in AlN/TiN multilayered system”, presented at ICTF-16, 13-16 October 2014, Dubrovnik, Croatia, published in Thin Solid Films (2015)

Country/Organization

Serbia

Type

scientific paper

Year

2015

Description

Pavlovic M., Miglierini M., Mustafin E., Ensinger W., Šagátová A. and Šoka M.: Radiation damage studies of soft magnetic metallic glasses irradiated with high-energy heavy ions, Radiation Effects & Defects in Solids, 2015

Country/Organization

Slovakia

Country/Organization

Publications are listed in the dissemination file in ROAD, please see above link.

Type

scientific paper

Year

2012

Description

M. A. Vicente Alvarez, J. R. Santisteban, P. Vizcaino, A. V. Flores, A. D. Banchik, and J. Almer, Hydride reorientation in Zr2.5Nb studied by synchrotron X-ray diffraction, Acta Materialia, vol. 60, no. 20, pp. 6892–6906, 2012.

Country/Organization

Argentina

Type

scientific paper

Year

2015

Description

Miglierini M., Hasiak M. and Bujdoš M.: Subsurface Structure and Magnetic Parameters of Fe-Mo-Cu-B Metallic Glass, Nukleonika 60 (2015) 115-119

Country/Organization

Slovakia

Type

scientific paper

Year

2013

Description

Heeley E.L., Gough T., Hughes D.J., Bras W., Rieger J., Ryan A.J.Effect of processing parameters on the morphology development during extrusion of polyethylene tape: An in-line small-angle X-ray scattering (SAXS) study. POLYMER 54(24), 2013, 6580-6588

Country/Organization

Netherlands

Type

scientific publication

Year

2014

Description

Valle F, Zuliani N, Marmiroli B, Amenitsch H, Taccani R.SAXS analysis of catalyst degradation in high temperature PEM fuel cells subjected to accelerated ageing tests Fuel Cells, Vol. 14 - 6, pp. 938-944 (2014)

Country/Organization

Italy/Elettra

Type

scientific paper

Year

2014

Description

P. Vizcaíno, J. R. Santisteban, M. A. Vicente Alvarez, A. D. Banchik, and J. Almer, Effect of crystallite orientation and external stress on hydride precipitation and dissolution in Zr2.5%Nb, Journal of Nuclear Materials, vol. 447, no. 1–3, pp. 82–93, 2014.

Country/Organization

Argentina

Type

scientific paper

Year

2013

Description

M. Milosavljevic, D. Toprek, M. Obradovic,A. Grce, D. Peruško, G. Dražic, J. Kovac, K.P. Homewood, „Ion irradiation induced solid-state amorphous reaction in Ni/Ti multilayers“ Applied Surface Science268 (2013) 516-523

Country/Organization

Serbia

Type

scientific paper

Year

2013

Description

M. A. Asri, Z. A. Z. Jamal, S. B. Jamaludin, N. Nafarizal, A. K. Othman, M. Z. Sadhan, M. P. Zakarita, M. Ionescu, J. Nowotny. Oxide Semiconductors for Solar to Chemical Energy Conversion: Nanotechnology approach. Intern. J. Ionics, 20(4) 581-592 (2013)

Country/Organization

Australia

Type

scientific book chapter

Year

2014

Description

A.J. Atanacio, T. Bak, D. Chu, M. Ionescu, J. Nowotny. Segregation-Induced Low-Dimensional Surface Structures in Oxide Seminconductors, in Handbook of Nanomaterials Properties, Ed: B. Bhushan, D. Luo, S. R. Schricker, W. Sigmund and S. Zauscher. Springer Berlin Heidelberg (2014). pp 891-910.

Country/Organization

Australia

Type

scientific publication

Year

2014

Description

S. Bosnar, D. Bosnar, B. Gr?eta, Positron Annihilation Lifetime Spectroscopy Study of the Formation of Mesoporous Materials from the Zeolite Precursor.Acta Phys. Pol. A125 (2014) 775.

Country/Organization

Croatia

Type

scientific paper

Year

2013

Description

Miglierini M.: Structural transformations in metallic glasses, Acta Electrotechnica et Informatica 13 (2013) 12-15

Country/Organization

Slovakia

Type

scientific paper

Year

2014

Description

R. K. Bommali, S. Ghosh, G. Vijaya Prakash, K. Gao, S. Zhou, S.A. Khan and P. Srivastava, “Hydrogen plasma induced modification of photoluminescence from a-SiNx:H thin films”.Journal of Applied Physics. 115 (2014) 053525.

Country/Organization

India

Type

scientific paper

Year

2014

Description

Nowotny, A. J. Atanacio, T, Bak, I. V. Belova, S. Fiechter, Y. Ikuma, M. Ionescu, B. J. Kennedy, P. Majewski, G. E. Murch, E D. Wachsman.Photosensitive oxide semiconductors for solar hydrogen fuel and water disinfection. International Materials Reviews 59(8) 449-478 (2014)

Country/Organization

Australia

Type

scientific paper

Year

2014

Description

Hessel L. Castricum, Goulven G. Paradis, Marjo C. Mittelmeijer-Hazeleger, Wim Bras, Guy Eeckhaut, Jaap F. Vente, Gadi Rothenberg, Johan E. ten Elshof. Tuning the nanopore structure and separation behavior of hybrid organosilica membranes.Microporous and Mesoporous Materials, 185, 2014, 224-234

Country/Organization

Netherlands

Type

scientific publication

Year

2014

Description

Fast neutron radiography at an RFQ accelerator system, G.C Daniels, C.B Franklyn, V. Dangendorf, A. Buffler, B. Bromberger, Conference proceedings10 World Conference on Neutron Radiography 5-10 October, 2014.

Country/Organization

South-Africa

Type

scientific paper

Year

2013

Description

C. Aramwit, S. Intarasiri, B. Supsermpol, N. Seanphinit, U. Tippawan, D. Bootkul, W.Ruangkul, L.D. Yu, “Synthesis and Characterization of Filtered-cathodic-vacuum-arc-deposited(FCVAD) TiO2 Films for Photovoltaic Applications Synthesis and Characterization of Filteredcathodic-vacuum-arc-deposited (FCVAD) TiO2 Films for Photovoltaic Applications,” J. of Physics, Conference Series (2013)

Country/Organization

Thailand

Type

scientific paper

Year

2013

Description

R. K. Bommali, S.P. Singh, G.Vijaya Prakash, S. Ghosh, P. Srivastava, Growth and Tailoring of Physical Properties of Si Quantum Dots in a-SiNx:H Matrix, Energy Procedia. 41 (2013) 50.

Country/Organization

India

Type

scientific paper

Year

2012

Description

M. Milosavljevic, A. Grce, D. Peruško, M. Stojanovic, J. Kovac, G. Dražic, A.Yu. Didyk, V.A. Skuratov, “A comparison of Ar ion implantation and swift heavy Xe ion irradiation effects on immiscible AlN/TiN multilayered nanostructures”, Materials Chemistry and Physics133 (2012) 884– 892.

Country/Organization

Serbia&Russia

Type

scientific publication

Year

2013

Description

Hu Y.-J., Knope KE, Skanthakumar S, Kanatzidis MG, Mitchell JF, Soderholm L, Understanding therole of aqueous solution speciation and its application to the directed syntheses of complex oxidic Zrchlorides and sulfates, , J. Am. Chem. Soc., Vol. 135 (38), pp 14240–14248 (2013).

Country/Organization

USA

Type

scientific paper

Year

2013

Description

Hu Y-J, Knope KE, Skanthakumar S, Kanatzidis MG, Mitchell JF, Soderholm L, J. Am. Chem. Soc.,Vol. 135 (38), pp 14240–14248 (2013).

Country/Organization

USA

Type

scientific paper

Year

2013

Description

E. G. Dere, H. Sharma, R. M. Huizenga, G. Portale, W. Bras, V. Bliznuk, J. Sietsma and S. E. Offerman. Formation of (Fe,Cr) carbides and dislocation structures in low-chromium steel studied in situ using synchrotron radiationJ. Applied Crystallography46, 2013, 181-192

Country/Organization

Netherlands

Type

scientific publication

Year

2015

Description

Douvali A, Tsipis AC, Eliseeva SV, Petoud S, Papaefstathiou GS, Malliakas CD, Papadas I, Armatas GS, Margiolaki I, Kanatzidis MG, Lazarides T, Manos MJ. Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework. Angew Chem Int Ed Engl. 2015, 54(5):1651-6.

Country/Organization

Greece

Type

scientific paper

Year

2013

Description

M. Milosavljevic, M. Obradovic,A. Grce, D. Peruško, D. Pjevic, J. Kovac, G. Dražic, C. Jeynes, „High dose ion irradiation effects on immiscible AlN/TiN nano-scaled multilayers“, Thin Solid Films544 (2013) 562-566.

Country/Organization

Serbia

Type

scientific paper

Year

2014

Description

Wim Bras, Satoshi Koizumi, Nicholas J. TerrillBeyond simple small-angle X-ray scattering: developments in online complementary techniques and sample environments.IUCrJ, 1(6), 2014, 478-91

Country/Organization

Netherlands

Type

scientific publication

Year

2014

Description

Bocchetta P, Gianoncelli A, Abyaneh MK, Kiskinova M, Amati M, Gregoratti L, Jezersek D, Mele C, Bozzini B. Electrosynthesis of Co/PPy nanocomposites for ORR electrocatalysis: a study based on quasi-in situ X-ray absorption, fluorescence and in situ Raman spectroscopy.Electrochimica Acta, Vol. 137, pp. 535-545 (2014)

Country/Organization

Italy/Elettra

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